Investigation of the effect of refining on the presence of targeted mineral oil aromatic hydrocarbons in coconut oil.

The goal of this work was to investigate the impact of refining on coconut oil particularly on the most toxicologically relevant fraction of the mineral oil aromatic hydrocarbon (MOAH) contamination, namely the fraction composed by the three to seven aromatic rings. A fully integrated platform consisting of a liquid chromatography (LC), a comprehensive multidimensional gas chromatography (GC) (LC-GC × GC) and flame ionization detector (FID) was used to obtained a more detailed characterization of the MOAH sub-classes distribution. The revised EN pr 16995:2017-08 official method was used for preparing the samples, both with and without the auxiliary epoxidation step. Crude coconut oil was spiked with different MOAH standards, namely naphthalenes, alkylated naphthalenes, benzo(a)pyrene, and its alkylated homologues. Refining was modelled by deodorization at 230 °C, stripping with 10 kg/h of steam under 1 mbar vacuum for 3 h. Complete removal of the naphthalenes and reduction of more than 98.8% of the benzo(a)pyrenes was observed. Epoxidation had a significant impact on the MOAH fraction with more than three rings, but with a high dependency on the sample matrix, being significantly less evident in the refined samples than in the crude ones.

The estimated intake of palm oil in Spain and Germany.

Palm oil is one of the most widely used vegetable oils by the food industry but there is limited information on actual intake. A detailed intake assessment of palm oil for Spain and Germany was conducted. For Spain, mean palm oil intakes ranged from 2.06 g/day in the elderly to 4.54 g/day in children and adolescents, while high-level intakes ranged from 10.34 g/day in the elderly to 20.88 g/day in toddlers. For Germany, mean palm oil intakes ranged from 3.06 g/day in toddlers to 6.22 g/day in the very elderly, while high-level intakes ranged from 13.61 g/day in toddlers to 30.10 g/day in the elderly. For both countries, the main contributing food categories to mean palm oil intake were biscuits, cakes, bread, breakfast cereal and margarine. In summary, the present paper provides a realistic assessment of the intake of palm oil in two EU countries for different population groups.